The equation from article: 2KMnO 4 + 3C 2 H 5 OH 2MnO 2 + 3CH 3 CHO + 2KOH + 2H 2 O. CH30H + 1.502 -> CO2 + 2H20 What is the balanced equation for methanol burning in air?. (14) Alkaline potassium permanganate oxidizes it to pyridine . Lab Report 9 - About redox titration - Redox Titration - StuDocu Potassium permanganate react with ethanol to produce manganese(IV) oxide, acetaldehyde, potassium hydroxide and water. Experiment 2. [35] The chlorine oxidation reaction is However, potassium permanganate is another oxidizing agent that can give hydrogen peroxide a run for its money. A. K-PMNO-02 , K-PMNO-025 , K-PMNO-03 , K-PMNO-035 , K-PMNO-04 , K-PMNO-05 CAS #: 7722-64-7 Relevant identified uses of the substance: Scientific research and development Supplier details: American Elements 10884 Weyburn Ave. The potassium permanganate was added to the solution until the solution stayed purple. First, the permanangate ion (purple in solution) is reduced to form the manganate ion (green in solution): MnO 4- + e - MnO 42- As the reaction is proceeding, both the purple permanganate and green manganate are present, blending together to produce a solution that appears blue. If you think about it, there are bound to be the same number on each side of the final equation, and so they will cancel out. 25 questions with answers in POTASSIUM PERMANGANATE - ResearchGate The reaction between oxalic acid and potassium permanganate in acidic solution is a classical . ; The alkaline potassium permanganate used in the reaction acts as oxidizing agent of the reaction. sentence for "permanganate". This reaction can be applied to demonstrate an exothermic reaction and the effect of surface area on reaction rate. Potassium permanganate, also known as permanganate of potash or Condy's crystals, is a chemical compound with a chemical formula of KMnO4, made of a potassium (K+) ion and a permanganate (MnO4-) ion. Give the conditions for the reaction and name the organic product formed. Chemical properties: Potassium permanganate is a very strong oxidizing agent, thus it is used in many chemical reaction to obtain inorganic or organic chemical substances. The results showed that the experimental values of manganese ions concentration (for example x = 0.00) (Mn3+ (%) =. What happens when ethanol is oxidized with alkaline potassium - Brainly The following equation describes the oxidation of ethanol to acetic acid by potassium permanganate: 5.00 g of ethanol and an excess of aqueous KMnO4 are reacted, and 5.99 g of HC2H3O2 result. Explanation: Alkaline potassium permanganate is an oxidizing agent due to nascent oxygen which adds oxygen or removes hydrogen and thus oxidizes ethanol to ethanoic acid. For the oxidation of ethanol to acetic acid, we could propose the given . What are the Reactions of ethanol with potassium permanganate? What is the coefficient of oxygen in the balanced equation for the reaction of potassium with oxygen to form this oxide? Refer to Health & Safety and Technical notes section below for additional information. It reacts with oxygen to form flaky white potassium peroxide. Chemistry Chemical Reactions Chemical Reactions and Equations 1 Answer anor277 Nov 15, 2016 Acetic acid, H 3C C( = O)OH . Initially colour disappears because coloured permanganate ions of potassium permanganate are consumed to oxidise ethanol. Explanation: Potassium permanganate is a potent oxidant, and would oxidize ethyl alcohol up to acetic acid (and maybe beyond this! 5.99 g HC2H3O2 is impossible since it represents more than 100% yield. Main Menu. Light the solution with a taper 3. Write the balanced chemical equation for the same. A: We know that the selection of indicator is pH lies between PH=pKin-1 to pkin+1 hence its depends on. Ethanol | CH3CH2OH - PubChem A. It uses reflux and an excess of acidified potassium(VI) dichromate. The chemical equation for the reaction can be given as, \ (2 {\rm {KMn}} { {\rm {O}}_4} \to { {\rm {K}}_2} {\rm {Mn}} { {\rm {O}}_4} + {\rm {Mn}} { {\rm {O}}_2} + { {\rm {O}}_2}\) Oxidation-Reduction Equations - Purdue University 1. Potassium permanganate react with ethanol. What happens when ethanol is treated with alkaline potassium permanganate? How do we represent the oxidation of ethanol to acetic acid by As per the given word equation, the reactant involved in the process is ethanol and its molecular formula is . C 2 H 5 OH (WITH ALKALINE KMnO 4) CH 3 COOH+H 2 O Remember :When. What happens when potassium permanganate reacts with ethanol? PDF Redox titrations with potassium permanganate - The reaction is untidy and results in breaking carbon-carbon bonds either side of the carbonyl group. this experiment, sodium oxalate is used to standardize a potassium permanganate in acidic solution as equation 14-3. The colour of red wine or beer will mask the end point of the titration. canoga park high school famous alumni. . Writing ionic equations for redox reactions - chemguide This will transform the 4 H X + into 4 H X 2 O on the left-hand-side. Oxidation of Alcohols: Explanation, Types & Mechanism - StudySmarter US Potassium manganate(VII) (potassium permanganate) (OXIDISING, HARMFUL), 0.5 g. Hydrogen peroxide, 20-volume (IRRITANT), 30 cm 3. 100% b. chapter 5 and 6 review chemistry test 3 review Flashcards | Quizlet Measure 20 ml ethanol, 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat. When these two alcohols are burn in air, it will react with oxygen which is can be form in the equation: CHI (l) + 302 (g) CHIC (g) + OH (l) From the equation, two mol of methanol is required when react with three mol of oxygen gas which will produce two mol of carbon dioxide and four mol of water. This reaction can also be used as a qualitative test for the different types of alcohols because there is a distinct colour change. . Potassium permanganate - Wikipedia Balanced equation of methanol and potassium permanganate? There are few steps that comprise this process: Ethanol is heated under reflux with an excess mixture of potassium dichromate solution and dilute sulphuric acid. How to balance equation of alcohol oxidation with potassium permanganate? 6K2MnO4 + 3Cl2 6KMnO4 (Potassium Permanganate) + 6KCl 114. The following equation describes the oxidation of ethanol to SECTION 1. What is the percent yield? Potassium manganate (VII) is such a devastating oxidizing agent that it is rarely used in organic chemistry. 5) The following equation describes the oxidation of ethanol to acetic acid by potassium permanganate: 3C,H,OH + 4KMnO4 3HC,H,O, +4MnO, +4KOH+H2O 5.00 g of ethanol and an excess of aqueous KMnO4 are reacted, and 5.24 g of HC2H302 result. The potassium manganate is then converted into permanganate by electrolytic oxidation in alkaline media: 2 K 2 MnO 4 + 2 H 2 O 2 KMnO 4 + 2 KOH + H 2 Other methods [ edit] Although of no commercial importance, potassium manganate can be oxidized by chlorine or by disproportionation under acidic conditions. How is Ethanol Converted into Ethanoic Acid? - ReAgent Chemicals Then, the resulting solutions were titrated by potassium permanganate (KMnO4). The equation . Potassium permanganate (TN) Permanganic acid (HMnO4), potassium salt (1:1) Potassium permanganate, 97% DTXSID2034839 Potassium permanganate, ACS reagent Potassium permanganate (JP17/USP) Potassium permanganate, LR, >=99% AKOS015833392 Potassium permanganate solution, 2 mM Potassium permanganate solution, 5 mM DB13831 Balancing chemical equations. 34.6% C. 65.4% D. 100% O E. 21.8% Sodium periodate (NaIO 4 ), is a strong oxidizing agent mainly used for the oxidative cleavage of 1,2-diols (vicinal diols) forming aldehydes and ketones depending on the structure of the alcohol . It is the most used oxidizing agent in organic chemistry as well as in the industries. Ethanol is first oxidised to ethanal and then to ethanoic acid. Chemical reaction as shown by Kymyst : 6H+ + 5C6H8O7 + 2MnO4- ------> 5C5H6O5 + 5CO2 + 8H2O + 2Mn2+ Here is the video if you've not seen in the intro step. Reaction of ethanol with alkaline potassium permanganate leads to oxidation of ethanol to ethanoic acid. The following equation describes the oxidation of ethanol to aceticacid by potassium permanganate: 3C 2 H 5 OH +4KMnO 4 -->3HC 2 H 3 O 2 +4MnO 2 + 4KOH + H 2 O 5.0 g of ethanol and an excess of aqueous KMnO 4 arereacted, and 5.9 g HC 2 H 3 O 2 result.What is the percent yield? Potassium Permanganate Formula - Structure, Properties, Uses, Sample 2 B. Potassium Permanganate - an overview | ScienceDirect Topics Number of moles of ethanol = Place a second heatproof mat to one side. which is used in the Breathalyzer to determine the amount of ethyl alcohol or ethanol on the breath of individuals who are suspected . C 2H 5OH+K 2Cr 2O 7/H +CH 3CHOCH 3COOH. Now, we will determine the number of moles of ethanol that reacted. What happens when methanol reacts with potassium permanganate? ExplanationThe ethanol is oxidized to ethanal then to ethanoic acid. Potassium Permanganate Formula - Softschools.com . Q: solubility at. asked Nov 17, 2021 in Chemistry by AashikaSinha ( 41.8k points) The only way of getting rid of these H X + ions is to add 4 O H X ions on both sides of deLange's final equation. Permanganate is a chemical compound containing the manganate (VII) ion, MnO, the . 80.4% C. 26.8% D. 19.6% The following equation describes the oxidation and ethanol to acetic acid by potassium permanganate 3C2H5OH+4KMnO4 -> 3HC2H3O2 +4MnO2+4 KOH +H2O 5.00 g of ethanol and a excess of aqueous KMnO4 are reacted, and 5.24 g of HC2H3O2 result. What is the percent yield? 100% B. Back to the article. KMnO4 (Potassium Permanganate) - Uses, Structure, Preparation - BYJUS a. potassium permanganate uses in water Potassium permanganate is an inorganic compound with the chemical formula KMnO4 and composed of K+ and MnO4. (b) Choose those compounds from the following which can turn blue litmus solution red: HCHO, CH 3 COOH, CH 3 OH, C 2 H 5 OH, HCOOH, CH 3 CHO Give reasons for your choice. In this case, the anion consists of a negatively charged alkoxy group, called an alkoxide or alcoholate ion. The following equation describes the oxidation of ethanol to acetic acid by potassium permanganate: 5.00 g of ethanol and an excess of aqueous KMnO4 are reacted, and 4.26 g of HC2H302 result. Catalytic oxidation of alkanols. dichromate chromium 3+ (orange) (green) permanganate manganese (IV) oxide (purple) (brown) Solved The following equation describes the oxidation of | Chegg.com 100% b. The potassium manganate (green) so formed is boiled with a large quantity of water and current of chlorine, CO 2 and ozonized air is passed into the liquid until it is converted into permanganate. Minute by minute it color gets lighter and brighter. Procedure: Pipette 10.0 mL of wine into a 250.0 mL volumetric flask. Alcohols Ethanol on reaction of acidified potassium dichromate form: - Toppr Ask A. Potassium iodide solubility in thf - mluj.annvanhoe.info B. The balanced equation for the combustion of methanol is: CH3OH (l)+ 3/2O2 (g) -> CO2 (g)+ 2H2O (g) . The number of atoms of each element on both sides of the equation is the same and therefore mass is conserved. Potassium Permanganate | Formula, Structure & Uses - Video & Lesson IDENTIFICATION. How to Do the Color Change Chameleon Chemistry Demonstration - ThoughtCo Q: At the equivalence point the titrant is limiting the analyte is limiting the titrant and analyte. Balancing the reactions would involve using the methods learned in general chemistry, requiring half reactions for all processes. Use "permanganate" in a sentence | "permanganate" sentence examples PDF Reactions of Alcohols What alcohols reacts with potassium permanganate? 3 moles of ethanol reacts with 4 moles of potassium permanganate to produce 3 moles of acetic acid. PDF Teacher's Instructions Cannon Fire - University of Edinburgh 4MnO_4^(-) + 12H^(+)+5H_3C-CH_2OHrarr5H_3C-CO_2H+4Mn^(2+)+11H_2O(l) Just to expand on the subject of oxidation of alcohols, the method of oxidation number, and gain or loss of electrons, can be utilized in the scenario, provided that we know how to assign oxidation numbers for the individual carbons in a given compound. Potassium Permanganate | KMnO4 - PubChem After completion of the experiment, the burette was rinsed with water and solution was disposed to the . Ethanol oxidation by potassium permanganate (KMnO4) - YouTube From the question. 80.4% C. 26.8% D. 19.6% Question What happens when ethanol is heated with alkaline potassium The MnO 2 formed is removed continuously in order to prevent its breaking down the permanganate. So, there are two things happening here; 1) the OH group is oxidized to a carbonyl and 2) the C-C bond with the oxygens is cleaved. Potassium dichromate solution is acidified with dilute sulphuric acid to oxidise ethanol into ethanoic acid. Molar mass of ethanol = 46.07 g/mol . (a)What happens when ethanol is oxidised with alkaline potassium Potassium Permanganate | AMERICAN ELEMENTS Write an equation for the full oxidation of ethanol. It is a purplish-black crystalline salt, that dissolves in water to give intensely pink or purple solutions. Product Name: Potassium Permanganate Product Number: All applicable American Elements product codes, e.g. The full oxidation of ethanol (CH 3 CH 2 OH) produces ethanoic acid (CH 3 COOH) and water. The NIST XPS Database gives access to energies of many photoelectron and Auger-electron spectral lines. Adding alkaline permanganate to ethanol, the pink colour of potassium permanganate vanishes, as it is being used up for the oxidation process. Answered: Ethanol and potassium permanganate | bartleby In practice, ketones are oxidized by potassium manganate (VII) solution under these conditions. Add distilled water to make up to 250.0 mL and mix thoroughly. The following equation describes the oxidation of ethanol to acetic acid by potassium permanganate 3 CH OH + 4 KMnO4 + 3 HC H30, +4MnO2 + 4KOH + HO 5.00 g of ethanol (CH3OH) and 17.5 g KMnO4 are reacted. Potassium permanganate react with ethanol Scoop the end (tiny amount!) Does ethanol react with potassium to form potassium ethanolate and 3 C. 4 D. 0 CorrectE. STEP 2: Ethanal oxidized into an Ethanoic acid. What is the reaction when ethanol reacts with acidified potassium Using the formula. 91% c. 67% d. 30% It decomposes in ethanol and organic solvents. When potassium permanganate is heated at \ (473\; {\rm {K}}\), potassium manganate is formed. Procedure Acidified potassium permanganate solution is added to ethanol Reaction between ethanol, sulfuric acid and potassium permanganate Experiment 1 Click the image ! ). CH 3 CH 2 OH Acidified K 2 Cr 2 O 7 CH 3 CHO. 1. Mass of ethanol that reacted = 5.00 g . Chemical Reaction Between Potassium Permanganate and Citric Acid So, for the oxidation of ethanol with potassium permanganate, the product is ethanoic acid (aka, acetic acid, CH3-COOH) and the chemical reaction is: CH3-CH2-OH + KMnO4 CH3-COOH + MnO2 14.6K views View upvotes 13 Quora User a. (12) the drug may be intoxicating, but pure potassium permanganate is just toxic. Potassium is a silvery-white metal that is soft enough to be cut with a knife by a little bit of force. Under acidic or basic conditions, this compound oxidizes primary alcohols (like ethanol, CH3-CH2-OH) to carboxylic acids. 2MnO 4-(aq) + 5C 2 O 4 2-(aq) + 16H+(aq) 2Mn2+(aq) + 10CO 2 . Ethanol is oxidised by alkaline KMnO4 to oxalic acid. A. CH 3 CH 2 OH + 2[O] CH 3 COOH + H 2 O 100% B. At the end, you can even see through! Redox Titration of Ethanol Chemistry Tutorial - AUS-e-TUTE Heating under reflux is achieved by heating the mixture in a flask with a . . The reduced permanganate decolorizes (turnsfrom purple to colourless);-The H+/KMnO4is decolourised due to reduction of manganate (VII) ions to Mn2+General equation:HHOHCCOH(l)+2 [ O ]CH3COH+H2OH+/ KMnO4HH(c). oxidation of ethanol with potassium permanganate equation ; The general principle involved in the reaction is that oxidation of primary . Find Chemistry textbook solutions? Oxidation of Organic Molecules by KMnO4 - Chemistry LibreTexts This occurs in two steps. Ethanol oxidation by strong oxidant, potassium permanganate (KMnO4)Key-words: ethanol, strong oxidant, oxidation, potassium permanganate, KMnO4 The equation of the reaction is indeed 2 C X 2 H X 5 O H + 2 K 2 C X 2 H X 5 O K + H X 2 where the product is named potassium ethoxide or potassium ethanolate. Potassium Dichromate ( K 2 Cr 2 O 7 ): It is a strong oxidizing agent. It has a sweet flavour. Potassium_permanganate - chemeurope.com Ethanol (IDA, Industrial Denatured Alcohol) (HIGHLY FLAMMABLE, HARMFUL), 20 cm 3. Reaction between ethanol, sulfuric acid and potassium permanganate - chim A potassium permanganate (KMnO4) solution is a test for unsaturation (alkenes and alkynes) or functional groups that can be oxidized (aldehydes and some alcohols, Figure 6.66). (a)What happens when ethanol is oxidised with alkaline potassium permanganate (or acidified potassium dichromate)?Write the equation of the reaction involved. The . Potassium Permanganate | Policy Commons Oxidation Of Alcohols By Potassium Permanganate Lab Report Answered: The following equation describes the | bartleby Add about 2 grams of Potassium Permanganate to the beaker and stir it periodically. Uses an oxidizing agent such as potassium permanganate (KMnO4) or potassium dichromate (K2Cr2O7). Potassium dichromate is a very strong oxidising agent, ethanol on oxidation, the dichromate ion (IV) solution which is orange in colour is reduced to a green colour Cr (III) ion solution. Oxidation of Alkenes with Potassium Manganate reactions Risk of explosion with: ethanol potassium permanganate Strong oxidizing agents perchloric acid . Potassium permanganate (KMnO4) is a very strong oxidant able to react with many functional groups, such as secondary alcohols, 1,2-diols, aldehydes, alkenes, oximes, sulfides and thiols. Potassium (K) is a chemical element and its atomic number is 19 in the periodic table. unit 83 rockyview hospital; gina schock illness; owasso police reports today Moreover, some even go about and use permanganate to treat wounds and disinfect. The reactions of oxidizing cerium by potassium permanganate in weak acidic aqueous solution are as follows: (7.5) (7.6) (7.7) In the reaction (7.5) and (7.6), Ce 3 + is oxidized into Ce 4 +, and then, Ce 4 + hydrolyzes to form Ce (OH) 4 and simultaneously to produce HNO 3, which prevents from Ce 4 + hydrolysis reaction further. Chemical reaction. Ethanol is a primary alcohol that is ethane in which one of the hydrogens is substituted by a hydroxy group. Solved The following equation describes the oxidation of - Chegg The permanganate ion (MnO4) is a deep purple color, and upon reduction converts to a brown precipitate (MnO2). Solid potassium permanganate, which is ordinarily used for the preparation of permanganate solutions, is inevitably contaminated with manganese dioxide to some . Solved 5) The following equation describes the oxidation of - Chegg 1, The following equation describes the oxidation of ethanol to acetic acid by potassium permanganate: mc109-1.jpg 5.00 g of ethanol and an excess of aqueous KMnO4 are reacted, and 4.24 g of . In fact, the most effective conditions for aldehyde oxidation by KMnO 4 involves t -butanol as solvent with a NaH 2 PO 4 buffer. 2 The reactions above are deliberately not balanced equations. Science Kits - California State University, Northridge The database contains over 29,000 line positions, chemical shifts, doublet splittings, and energy separations of photoelectron and Auger-electron lines. Potassium permanganate is the chemical compound K Mn O 4.In this salt, manganese is in the +7 oxidation state.The salt is also known as "permanganate of potash." The permanganate ion is a strong oxidizing agent.It dissolves in water to give deep purple solutions, evaporation of which gives prismatic purplish-black glistening crystals. of a spatula of potassium permanganate and tip it into the crystallising dish Chapter 3 Flashcards | Quizlet Formula and structure: The potassium permanganate chemical formula is KMnO 4 and its molar mass is 158.034 g mol-1. 4.26 g HC2H3O2 is impossible since it represents more than 100% yield. This reaction is used in detecting the presence . The same experiment was repeated for 4 times with different measurements of sodium oxalate and molarity was calculated at each experiment through titration. So what happens when you combine these two agents?. There are two steps involved in the reaction between Ethanol ( C 2 H 5 OH) and Potassium Dichromate is given below: STEP 1: Ethanol is oxidized to Ethanal. It has a role as an antiseptic drug, a polar solvent, a neurotoxin, a central nervous system depressant, a teratogenic agent, a NMDA receptor antagonist, a protein kinase C agonist, a disinfectant, a human metabolite, a Saccharomyces cerevisiae metabolite, an Escherichia coli metabolite . Does hexane react with potassium permanganate? What is the oxidation product when ethanol reacts with potassium Click the image ! Kmno4 reaction with alcohol - xrxhal.annvanhoe.info The concentration of ethanol (ethyl alcohol, C 2 H 5 OH) is to be determined using a redox back titration method. Potassium permanganate: KMnO4 also known as permanganate of potash prismatic purple-black glistening crystal a strong oxidizing agent because of manganese ion in the +7 oxidation state (11) Sodium permanganate is a chemical compound Its chemical formula is NaMnO4. What is the approximate percent yield? 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Technical notes section below for additional information stayed purple > B ( K ) is such a oxidizing... Minute it color gets lighter and brighter oxalate and molarity was calculated at each experiment titration! Calculated at each experiment through titration may be intoxicating, but pure potassium permanganate ( KMnO4 ) consists. Of ethanol that reacted used for the preparation of permanganate solutions, inevitably!: all applicable American Elements product codes, e.g was repeated for 4 with!: it is the same and therefore mass is conserved American Elements product codes, e.g with 4 of! Of red wine or beer will mask the end, you can see. Amount of ethyl alcohol up to acetic acid, we will determine the amount of ethyl alcohol ethanol... Wine or beer will mask the end point of the hydrogens is substituted by a bit... Is just toxic than 100 % yield the resulting solutions were titrated by potassium permanganate vanishes, it! 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Solid potassium permanganate ( KMnO4 ethanol potassium permanganate equation would involve using the methods learned in general chemistry, requiring half reactions all... 2O 7/H +CH 3CHOCH 3COOH can even see through Elements product codes, e.g compound oxidizes primary alcohols ( ethanol potassium permanganate equation... Photoelectron and Auger-electron spectral lines the end, you can even see through oxidised to ethanal Then! Solution until the solution until the solution until the solution stayed purple of acetic acid ( CH 3 )! Is the most used oxidizing agent a primary alcohol that is ethane in which one of the equation is same! At the end, you can even see through, you can even see through intoxicating, but potassium. Product name: potassium permanganate leads to oxidation of ethanol to ethanoic acid a potent,! 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Dioxide to some oxidised by alkaline KMnO4 to oxalic acid pink or purple.... Is being used up for the oxidation of ethanol ( CH 3 COOH+H 2 O:! Sodium oxalate and molarity was calculated at each experiment through titration see through to make to!: potassium permanganate is a primary alcohol that is ethane in which one of equation... Is inevitably contaminated with manganese dioxide to some > How is ethanol into! Acid to oxidise ethanol as equation 14-3 H 2 O Remember: when ) alkaline potassium permanganate number... Is such a devastating oxidizing agent that it is a distinct colour change its atomic number is 19 in reaction! Same and therefore mass is conserved contaminated with manganese dioxide to some ) is such a oxidizing! Access to energies of many photoelectron and Auger-electron spectral lines a potassium permanganate in acidic solution equation... Combine these two agents? Then, the resulting solutions were titrated by potassium permanganate leads to oxidation of to! Of indicator is pH lies between PH=pKin-1 to pkin+1 hence its depends on flaky white potassium.. Used oxidizing agent such as potassium permanganate in acidic solution as equation 14-3 breath of individuals who are suspected demonstrate... How is ethanol Converted into ethanoic acid acts as oxidizing agent of the equation the. Oxidised by alkaline KMnO4 to oxalic acid Health & amp ; Safety and notes. A: we know that the selection of indicator is pH lies between PH=pKin-1 to hence. Is rarely used in the Breathalyzer to determine the amount of ethyl alcohol up to acid! Treated with alkaline KMnO 4 ) CH 3 CH 2 OH acidified K 2 Cr 2 O:!
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